Jonathan welcomes pop sensation Cheryl Cole, who will be chatting and performing live in the studio. She is joined by actor Kayvan Novak, musical legend Andrew Lloyd Webber, the cast of Jesus Christ Superstar, Mel C, Tim Minchin, and Ben Foster.
| Name | Type | Role | |
|---|---|---|---|
| Cheryl | Musical Guest | ||
| Cheryl | Guest Star | Guest | |
| Andrew Lloyd Webber | Guest Star | Guest | |
| Kayvan Novak | Guest Star | Guest | |
| Melanie C | Guest Star | Guest | |
| Ben Foster | Guest Star | Guest | |
| Tim Minchin | Guest Star | Guest |